TERBIUM

• Atomic Number: 65
• Atomic Symbol: Tb
• Atomic Weight: 158.9254
• Electron Configuration: -26-9-2

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History:

(Ytterby, a villiage in Sweden) Discovered by Mosander in 1843. Terbium is a member of the lanthanide or "rare earth" group of elements. It is found in cerite, gadolinite, and other minerals along with other rare earths. It is recovered commercially from monazite in which it is present to the extent of 0.03%, from xenotime, and from euxenite, a complex oxide containing 1% or more of terbia. Terbium has been isolated only in recent years with the development of ion-exchange techniques for separating the rare-earth elements. As with other rare earths, it can be produced by reducing the anhydrous chloride or fluoride with calcium metal in a tantalum crucible. Calcium and tantalum impurities can be removed by vacuum remelting. Other methods of isolation are possible. Terbium is reasonably stable in air. It is a silver-gray metal, and is malleable, ductile, and soft enough to be cut with a knife. Two crystal modifications exist, with a transformation temperature of 1289C. Twenty one isotopes with atomic masses ranging from 145 to 165 are recognized. The oxide is a chocolate or dark maroon color. Sodium terbium borate is used in solid-state devices. The oxide has potential application as an activator for green phosphors used in color TV tubes. It can be used with ZrO2 as a crystal stabilizer of fuel cells which operate at elevated temperature. Few other uses have been found. The element is priced at about $30/g (99.9%). Little is known of the toxicity of terbium. It should be handled with care as with other lanthanide elements.

Source: CRC Handbook of Chemistry and Physics, 1913-1995. David R. Lide, Editor in Chief. Author: C.R. Hammond