DYSPROSIUM
- Atomic Number: 66
- Atomic Symbol: Dy
- Atomic Weight: 162.50
- Electron Configuration: -28-8-2
History:
-
(Gr. dysprositos, hard to get at) Dysprosium was discovered in 1886
by Lecoq de Boisbaudran, but not isolated. Neither the oxide nor the
metal was available in relatively pure form until the development of
ion-exchange separation and metallographic reduction techniques by
Spedding and associates about 1950. Dysprosium occurs along with
other so-called rare-earch or lanthanide elements in a variety of
minerals such as xenotime, fergusonite, gadolinite, euxenite,
polycrase, and blomstrandine. The most important sources, however,
are from monaziate and bastnasite. Dysprosium can be prepared by
reduction of the trifluoride with calcium. The elemtn has a
metallic, bright silver luster. It is relatively stable in air at
room temperature, and is readily attacked and dissolved, with the
evolution of hydrogen, but dilute and concentrated mineral acides.
The metal is soft enough to be cut with a knife and can be machined
without sparking if overheating is avoided. Small amounts of
impurities can greatly affect its physical properties. While
dysprosium has not yet found many applications, its thermal neutron
absorption cross-section and high melting point suggest metallurgical
uses in nuclear control applications and for alloying with special
stainless steels. A dysprosium oxide-nickel cermet has found use in
cooling nuclear reactor rods. This cermet absorbs neutrons readily
without swelling or contracting under prolonged neutron bombardment.
In combination with vanadium and other rare earths, dysprosium has
been used in making laser materials. Dysprosium-cadmium
chalcogenides, as sources of infrared radiation, have been used for
studying chemical reactions. The cost of dysprosium metal has
dropped in recent years since the development of ion-exchange and
solvent extraction techniques, and the discovery of large ore bodies.
The metal costs about $300/kg in purities of 99+%.
Source: CRC Handbook of Chemistry and Physics, 1913-1995. David R. Lide, Editor in Chief. Author: C.R. Hammond
Copyright ©1995-1998
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