ERBIUM
- Atomic Number: 68
- Atomic Symbol: Er
- Atomic Weight: 167.26
- Electron Configuration: -30-8-2
History:
-
(Ytterby, a town in Sweden) Erbium, one of the so-called rare-earth
elements on the lanthanide series, is found in the minerals mentioned
under dysprosium. In 1842 Mosander separated "yttria" found in the
mineral gadolinite, into three fractions which he called yttria,
erbia, and terbia. The names erbia and terbia became confused in
this early period. After 1860, Mosander's terbia was known as erbia,
and after 1877, the earlier known erbia became terbia. The erbia of
this period was later shown to consist of five oxides, now known as
erbia, scandia, holmia, thulia and ytterbia. By 1905 Urbain and
James independently succeeded in isolating fairly pure Er2O3. Klemm
and Bommer first produced reasonably pure erbium metal in 1934 by
reducing the anhydrous chloride with potassium vapor. The pure metal
is soft and malleable and has a bright, silvery, metallic luster. As
with other rare-earth metals, its properties depend to a certain
extent on the impurities present. The metal is fairly stable in air
and does not oxidize as rapidly as some of the other rare-earth
metals. Naturally occurring erbium is a mixture of six isotopes, all
of which are stable. Nine radioactive isotopes of erbium are also
recognized. Recent production techniques, using ion-exchange
reactions, have resulted in much lower prices of the rare-earch metals
and their compounds in recent years. The cost of 99+% erbium metal
is about $650/kg. Erbium is finding nuclear and metallurgical uses.
Added to vanadium, for example, erbium lowers the hardness and
improves workability. Most of the rare-earth oxides have sharp
absorption bands in the visible, ultraviolet, and near infrared.
This proerty, associated with the electronic structure, gives
beautiful pastel colors to many of the rare-earth salts. Erbium
oxide gives a pink color and has been used as a colorant in glasses
and porcelain enamel glazes.
Source: CRC Handbook of Chemistry and Physics, 1913-1995. David R. Lide, Editor in Chief. Author: C.R. Hammond
Copyright ©1995-1998
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